苗成霞

个人基本简介

职称：教授

学位：博士

毕业院校：南开大学

电子邮件：chxmiao@sdau.edu.cn 或者chengxiamiao@163.com

苗成霞，博士，教授，中科院青年创新促进会会员，山东省青年创新人才引育团队负责人。主要讲授本科生的《有机化学》、《绿色化学》、《有机化学实验》《基础化学实验》等课程。研究工作一直以“绿色精准化”为原则，开展绿色催化与合成方面的研究，实现了二氧化碳、醇和烯烃等化合物的清洁转化制备重要化工中间体或药物中间体。先后主持国家自然科学基金面上项目、青年基金项目及省级面上项目等多项课题；获得中科院西部之光和中科院青年创新促进会会员等项目支持。目前以第一作者或者通讯作者在J. Am. Chem. Soc., Chem. Sci., Green Chem., Adv. Synth. Catal.等化学类top期刊上发表SCI论文40余篇；参与撰写《绿色化学基本原理》《二氧化碳化学》《离子液体百科全书》和《有机合成试剂百科全书》等中英文专著；授权中国发明专利3件。

主要经历

学科方向

二氧化碳的化学转化与利用

重要化工/药物中间体的绿色催化与合成

清洁催化氧化

生物质基功能化材料的设计合成与催化应用

荣誉获奖

2023年 山东农业大学“最美教师提名奖”

2020年 山东农业大学“青年岗位能手”

2015年 入选中科院青年创新促进会第五批会员

2015年 获天津市自然科学三等奖

科研项目

国家自然科学基金面上项目(21972079)：新型多功能四氮铁配合物的创制及催化烯烃/CO₂一步合成环状碳酸酯的研究，2020.01-2023.12，主持

山东省自然科学基金面上项目(ZR2019MB002)：基于新型水溶性四氮金属配合物的仿生催化烯烃双羟化反应的研究，2019.07-2022.06，主持

山东省高等学校青年创新团队人才引育计划：绿色催化与合成，2020.01-2022.12，主持

江苏省自然科学基金面上项目(BK20161261)：质子和阴离子协同促进非血红素金属配合物催化氧化反应的研究，2016.07-2019.06，主持

煤炭高效利用与绿色化工国家重点实验室开放课题：新型离子液体的创制及其在二氧化碳活化转化中的应用研究，2019.01-2020.12，主持

代表文章

Hongfeng Zhuang, Qin Hou, Feng Han,* Haotian Lv and Chengxia Miao*（通讯）, Heteropolyacid catalyzed O-alkylation of oximes with alcohols via a carbocation in dimethyl carbonate and mechanism insight, Green Chem., 2023, 25, 310-317.

Qiaowen Liu, Feng Han,* Hongfeng Zhuang, Tong Zhang, Na Ji and Chengxia Miao*（通讯）, Direct deoxygenation of active allylic alcohols via metal-free catalysis, Org. Biomol. Chem., 2022, 20, 1680-1689.

Haotian Lv, Feng Han,* Ning Wang, Nan Lu,* Zenghong Song, Jian Zhang, and Chengxia Miao*（通讯）, Ionic liquid-catalyzed C-C bond formation for the synthesis of polysubstituted olefins, Eur. J. Org. Chem. 2022, e202201222.

Qiaowen Liu, Feng Han,* Hongfeng Zhuang, Zenghong Song, Jian Zhang, Tong Zhang, Ning Wang, and Chengxia Miao*（通讯）, Acidic ionic liquids as metal-free and recyclable catalysts for direct reduction of aromatic allylic alcohol in dimethyl carbonate via hydrogen transfer, ACS Sustainable Chem. Eng., 2022, 10, 6784−6793.

Ning Wang, Zengmin Li, Qin Hou, Feng Han,* Yucai Yan, Jian Zhang, and Chengxia Miao*（通讯）, Metal-free, adjustable, and recyclable catalytic systems for the construction of C−C bonds by activating propargylic alcohols. J. Org. Chem., 2022, 87, 11669-11680.

Feng Han, Heng Li, Hongfeng Zhuang, Qin Hou, Qingfeng Yang, Bing Zhang, Chengxia Miao*（通讯）,Direct synthesis of cyclic carbonates from olefins and CO₂: Single- or multi-component catalytic systems via epoxide or halohydrin intermediate, J. CO₂ Util., 2021, 53, 101742.

Zengmin Li, Yating Wen, Ning Wang, Feng Han*, Ying Li, Hongfeng Zhuang, and Chengxia Miao*（通讯）, Ionic liquids with multi-active sites synergistically catalyzed metal-free transformation of alcohols using dimethyl carbonate as an environmental solvent, Eur. J. Org. Chem., 2021, 3819-3826.

Hongfeng Zhuang, Nan Lu, Na Ji, Feng Han, Chengxia Miao*（通讯）, Bu₄NHSO₄-catalyzed direct N-allylation of pyrazole and its derivatives with allylic alcohols in water: A metal-free, recyclable and sustainable system, Adv. Synth. Catal. 2021, 363, 5461-5472.

Hongfeng Zhuang, Heng Li, Shuai Zhang, Yanbin Yin, Feng Han*, Chao Sun, Chengxia Miao*（通讯）, TEMPO and its derivatives mediated reactions under transition-metal-free conditions, Chin. Chem. Lett., 2020, 31(1), 39-48.

Chengxia Miao, Qin Hou, Yating Wen, Feng Han,* Zhen Li, Lei Yang, and Chun-Gu Xia, Long-chained acidic ionic liquids-catalyzed cyclization of 2-substituted aminoaromatics with β diketones: A metal-free strategy to construct benzoazoles, ACS Sustainable Chem. Eng.,2019, 7, 12008−12013.

Chengxia Miao, Xiao-Xi Li, Yong-Min Li, Chungu Xia, Yong Wang, Wonwoo Nam, Wei Sun, Manganese complex-catalyzed oxidation and oxidative kinetic resolution of secondary alcohols by hydrogen peroxide. Chem. Sci., 2017,8, 7476-7482.

Chengxia Miao, Bin Wang, Yong Wang, Chungu Xia, Yong-Min Lee, Wonwoo Nam*, and Wei Sun*, Proton-promoted and anion-enhanced epoxidation of olefins by hydrogen peroxide in the presence of nonheme manganese catalysts.J. Am. Chem. Soc., 2016, 138, 936-943.